Ontology highlight
ABSTRACT:
SUBMITTER: Baggett AW
PROVIDER: S-EPMC6190573 | biostudies-literature | 2017 Oct
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20171011 42
Upon reaction with either molecular oxygen or di-tert-butylperoxide in the presence of a simple copper(I) salt and an alcohol, a range of 1,2-azaborines readily exchange B-alkyl or B-aryl moieties for B-alkoxide fragments. This transformation allows alkyl and aryl groups to serve for the first time as removable protecting groups for the boron position of 1,2-azaborines during reactions that are not compatible with the easily modifiable B-alkoxide moiety. This reaction can be applied to synthesiz ...[more]