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Modular Synthesis of Polymers Containing 2,5-di(thiophenyl)-N-arylpyrrole.


ABSTRACT: A modular facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility.

SUBMITTER: Truong TNB 

PROVIDER: S-EPMC6192053 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature

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Modular Synthesis of Polymers Containing 2,5-di(thiophenyl)-N-arylpyrrole.

Truong Tran N B TNB   Savagatrup Suchol S   Jeon Intak I   Swager Timothy M TM  

Journal of polymer science. Part A, Polymer chemistry 20180322 11


A modular facile route has been developed to synthesize functionalized 2,5-di(thiophen-2-yl)-1-H-arylpyrroles from readily available starting materials. These units are compatible with various polymerization conditions and are versatile building blocks for conjugated polymers. The polymers show high thermal stability and solubility in a number of solvents. Characterization of the polymers reveals a correlation between molecular packing, controllable by polymer design, and charge carrier mobility  ...[more]

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