Ontology highlight
ABSTRACT:
SUBMITTER: Brito GA
PROVIDER: S-EPMC6205292 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Organic letters 20180625 13
Cyclometalated π-allyliridium C,O-benzoates modified by ( S)-SEGPHOS or ( S)-Cl,OMe-BIPHEP catalyze enantioselective 2-propanol-mediated reductive couplings of diverse nonmetallic allyl pronucleophiles with the acetylenic aldehyde TIPSC≡CCHO. Absolute stereochemistries of the resulting secondary homoallylic-propargylic alcohols were assigned using Rychnovsky's competing enantioselective conversion method. ...[more]