Unknown

Dataset Information

0

Self-structuring in Zr1-xAlxN films as a function of composition and growth temperature.


ABSTRACT: Nanostructure formation via surface-diffusion-mediated segregation of ZrN and AlN in Zr1-xAlxN films during high mobility growth conditions is investigated for 0???×???1. The large immiscibility combined with interfacial surface and strain energy balance resulted in a hard nanolabyrinthine lamellar structure with well-defined (semi) coherent c-ZrN and w-AlN domains of sub-nm to ~4?nm in 0.2???×???0.4 films, as controlled by atom mobility. For high AlN contents (x?>?0.49) Al-rich ZrN domains attain wurtzite structure within fine equiaxed nanocomposite wurtzite lattice. Slow diffusion in wurtzite films points towards crystal structure dependent driving force for decomposition. The findings of unlikelihood of iso-structural decomposition in c-Zr1-xAlxN, and stability of w-Zr1-xAlxN (in large × films) is complemented with first principles calculations.

SUBMITTER: Ghafoor N 

PROVIDER: S-EPMC6218527 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature

altmetric image

Publications

Self-structuring in Zr<sub>1-x</sub>Al<sub>x</sub>N films as a function of composition and growth temperature.

Ghafoor N N   Petrov I I   Holec D D   Greczynski G G   Palisaitis J J   Persson P O A POA   Hultman L L   Birch J J  

Scientific reports 20181105 1


Nanostructure formation via surface-diffusion-mediated segregation of ZrN and AlN in Zr<sub>1-x</sub>Al<sub>x</sub>N films during high mobility growth conditions is investigated for 0 ≤ × ≤ 1. The large immiscibility combined with interfacial surface and strain energy balance resulted in a hard nanolabyrinthine lamellar structure with well-defined (semi) coherent c-ZrN and w-AlN domains of sub-nm to ~4 nm in 0.2 ≤ × ≤ 0.4 films, as controlled by atom mobility. For high AlN contents (x > 0.49) Al  ...[more]

Similar Datasets

| S-EPMC9125986 | biostudies-literature
| S-EPMC5430970 | biostudies-literature
| S-EPMC7915223 | biostudies-literature
| S-EPMC6641164 | biostudies-literature
| S-EPMC8567257 | biostudies-literature
| S-EPMC7200746 | biostudies-literature
| S-EPMC7345939 | biostudies-literature
| S-EPMC4836877 | biostudies-literature
| S-EPMC8605440 | biostudies-literature
| S-EPMC8093203 | biostudies-literature