Synthesis of O-1- O-6 Substituted Positional Isomers of d-Glucose-Thioether Ligands and Their Ruthenium Polypyridyl Conjugates.
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ABSTRACT:
SUBMITTER: Lameijer LN
PROVIDER: S-EPMC6218880 | biostudies-literature | 2018 Nov
REPOSITORIES: biostudies-literature
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Synthesis of O-1- O-6 Substituted Positional Isomers of d-Glucose-Thioether Ligands and Their Ruthenium Polypyridyl Conjugates.
Lameijer Lucien N LN le Roy Julien J van der Vorm Stefan S Bonnet Sylvestre S
The Journal of organic chemistry 20181023 21
A library of positional isomers of d-glucose ( O-1- O-6) as ligands and their 11 light-active ruthenium conjugates has been synthesized. A protecting group strategy without the necessity of using palladium on carbon for the modification for the 2- O and 4- O position allows for the incorporation of sulfur donor atoms as ligands for transition metal complexes. ...[more]
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