Reversible Mechanochromic Delayed Fluorescence in 2D Metal-Organic Micro/Nanosheets: Switching Singlet-Triplet States through Transformation between Exciplex and Excimer.

ABSTRACT: Mechanochromic luminescent materials have attracted much attention and present a variety of applications in information security, data recording, and storage devices. However, most of these smart luminescent systems are based on typical fluorescence and/or phosphorescence mechanisms; the mechanochromic delayed fluorescence (MCDF) materials involving switching singlet and triplet states are rarely studied to date. Herein, new 2D layered metal-organic micro/nanosheets, [Cd(9-AC)₂(BIM)₂] (named as MCDF-1; 9-AC = anthracene-9-carboxylate and BIM = benzimidazole) and its solvate form containing interlayer CH₃CN (named as MCDF-2), which exhibit reversible mechanochromic delayed fluorescence characteristics, are presented. With applying the mechanical force, the luminescent center of MCDF-1 can be converted from 9-AC/BIM exciplex to 9-AC/9-AC excimer, resulting in alternations of delayed fluorescence. Such luminescent change can be further recovered by CH₃CN fumigation, accompanied by the structural transformation from MCDF-1 to MCDF-2. Furthermore, the force-responsive process also refers to the energy redistribution between singlet and triplet states as inferred by both temperature-dependent photophysics and theoretical calculations. Therefore, this work not only develops new 2D micro/nanosheets as MCDF materials, but also supplies a singlet-triplet energy switching mechanism on their reversible mechanochromic process.

SUBMITTER: Yang Y 

PROVIDER: S-EPMC6247076 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature