Ontology highlight
ABSTRACT:
SUBMITTER: Weitz AC
PROVIDER: S-EPMC6263813 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
Weitz Andrew C AC Hill Ethan A EA Oswald Victoria F VF Bominaar Emile L EL Borovik Andrew S AS Hendrich Michael P MP Guo Yisong Y
Angewandte Chemie (International ed. in English) 20181114 49
Hydrogen bonds (H-bonds) have been shown to modulate the chemical reactivities of iron centers in iron-containing dioxygen-activating enzymes and model complexes. However, few examples are available that investigate how systematic changes in intramolecular H-bonds within the secondary coordination sphere influence specific properties of iron intermediates, such as iron-oxido/hydroxido species. Here, we used <sup>57</sup> Fe nuclear resonance vibrational spectroscopy (NRVS) to probe the Fe-O/OH v ...[more]