Breakdown of the Stokes-Einstein relation above the melting temperature in a liquid phase-change material.

ABSTRACT: The dynamic properties of liquid phase-change materials (PCMs), such as viscosity ? and the atomic self-diffusion coefficient D, play an essential role in the ultrafast phase switching behavior of novel nonvolatile phase-change memory applications. To connect ? to D, the Stokes-Einstein relation (SER) is commonly assumed to be valid at high temperatures near or above the melting temperature T _m and is often used for assessing liquid fragility (or crystal growth velocity) of technologically important PCMs. However, using quasi-elastic neutron scattering, we provide experimental evidence for a breakdown of the SER even at temperatures above T _m in the high-atomic mobility state of a PCM, Ge₁Sb₂Te₄. This implies that although viscosity may have strongly increased during cooling, diffusivity can remain high owing to early decoupling, being a favorable feature for the fast phase switching behavior of the high-fluidity PCM. We discuss the origin of the observation and propose the possible connection to a metal-semiconductor and fragile-strong transition hidden below T _m.

SUBMITTER: Wei S 

PROVIDER: S-EPMC6269161 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature