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Palladium(II)-catalyzed othro-C-H-benzoxylation of 2-arylpyridines by oxidative coupling with aryl acylperoxides.


ABSTRACT: A palladium(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with aryl acylperoxides was developed. With pyridyl as directing group, the benzoxylation reaction exhibits remarkable regioselectivity and excellent functional group tolerance, providing the products in up to 87% yield.

SUBMITTER: Sit WN 

PROVIDER: S-EPMC6270440 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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Palladium(II)-catalyzed othro-C-H-benzoxylation of 2-arylpyridines by oxidative coupling with aryl acylperoxides.

Sit Wing-Nga WN   Chan Chun-Wo CW   Yu Wing-Yiu WY  

Molecules (Basel, Switzerland) 20130415 4


A palladium(II)-catalyzed ortho-benzoxylation of 2-arylpyridines with aryl acylperoxides was developed. With pyridyl as directing group, the benzoxylation reaction exhibits remarkable regioselectivity and excellent functional group tolerance, providing the products in up to 87% yield. ...[more]

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