Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex.
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ABSTRACT:
SUBMITTER: Pitto-Barry A
PROVIDER: S-EPMC6275942 | biostudies-literature | 2018 Nov
REPOSITORIES: biostudies-literature
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Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex.
Pitto-Barry Anaïs A Barry Nicolas P E NPE
ACS omega 20181116 11
A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO<sub>(g)</sub>. Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule. ...[more]
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