Physiochemical characteristics and oxidative potential of ambient air particulate matter (PM10) during dust and non-dust storm events: a case study in Tehran, Iran.
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ABSTRACT: In the present study, we investigated the characteristics of metal(loid)s, polycyclic aromatic hydrocarbons (PAHs) and oxidative potential (OP) in PM10 during dust and non-dust days in a rural and an urban area in Tehran. Water-soluble ions, metal(loid)s, PAHs, and OP were measured using ion chromatography (IC), inductively coupled plasma optical emission spectrometer (ICP-OES) and gas chromatography/mass spectrometry (GC-MS), and dithiothreitol (DTT) assay respectively. The results showed that the average concentrations of ambient PM10 were 284?±?90.4 and 123?±?31.4 ?g m-3 on dusty and regular days in urban areas respectively, and were 258?±?48.3 and 124?±?41.4 ?g m-3 on dusty and regular days in rural areas, respectively; these values were 95% above the World Health Organization (WHO) guideline level. The crustal elements Na+, Mg2+, Ca2+, Al, Si, Fe and Ti were the dominant for PM10 on dusty days, and NO- 3 and SO4 2- were dominant for PM10 on regular days. The average?±?SD concentrations of total PAHs were 34.3?±?22.5 and 55.1?±?28.3 ng m-3 on dusty and regular days, respectively, with the maximum value occurring on inversion days. The average OP was 8.90?±?7.15 and 1.41?±?0.35 and was 11.4?±?3.97 and 19.9?±?8.67 (nmol min-1 ?g PM10 -1) for water and methanol extracts on dusty and regular days, respectively, with the lowest value occurring on dusty days. The OP was highly associated with Cu and Mn. Briefly; the results of this study demonstrate that OP is mass independent and consequence a promising proxy for PM mass.
SUBMITTER: Rezaei S
PROVIDER: S-EPMC6277329 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
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