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Crystal structure and Hirshfeld surface analysis of (succinato-?O)[N,N,N',N'-tetra-kis-(2-hy-droxy-eth-yl)ethyl-enedi-amine-?5 O,N,N',O',O'']nickel(II) tetra-hydrate.

ABSTRACT: In the title compound, [Ni(C10H24N2O4)(C4H4O4)]·4H2O, the NiII cation is octa-hedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N',N'-tetra-kis-(2-hy-droxy-eth-yl)ethyl-enedi-amine mol-ecule. In the crystal, mol-ecules are linked by O-H?O and C-H?O hydrogen bonds, forming a three-dimensional supra-molecular architecture. Hirshfeld surface analyses and two-dimensional fingerprint plots were used to analyse the inter-molecular inter-actions present in the crystal, indicating that the most important contributions for the crystal packing are from H?H (63.3%) and H?O/O?H (34.5%) inter-actions.

SUBMITTER: Kansiz S

PROVIDER: S-EPMC6281127 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N',N'-tetra-kis-(2-hy-droxy-eth-yl)ethyl-enedi-amine-κ5 O,N,N',O',O'']nickel(II) tetra-hydrate.

Kansiz Sevgi S Dege Necmi N Topcu Yildiray Y Atalay Yusuf Y Gaidai Snizhana V SV

Acta crystallographica. Section E, Crystallographic communications 20181106 Pt 12

In the title compound, [Ni(C10H24N2O4)(C4H4O4)]·4H2O, the NiII cation is octa-hedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N',N'-tetra-kis-(2-hy-droxy-eth-yl)ethyl-enedi-amine mol-ecule. In the crystal, mol-ecules are linked by O-H⋯O and C-H⋯O hydrogen bonds, forming a three-dimensional supra-molecular architectu ...[more]

PMID: 30574359

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