A one-dimensional iodido-bridged Pt^II/Pt^IV mixed-valence complex cation with a hydrogen sulfate counter-anion.

ABSTRACT: The title compound, catena-poly[[[bis-(ethyl-enedi-amine-κ² N,N')platinum(II)]-μ-iodido-[bis-(ethyl-enedi-amine-κ² N,N')platinum(IV)]-μ-iodido] tetra-(hydrogen sulfate) dihydrate], {[Pt^II(C₂H₈N₂)₂][Pt^IVI₂(C₂H₈N₂)₂](HSO₄)₄·2H₂O} _n , has a linear chain structure comprising alternating platinum cations with mixed-valent oxidation states of +II/IV. Square-planar [Pt(en)₂]²⁺ cations and elongated octa-hedral trans-[PtI₂(en)₂]²⁺ cations (en is ethyl-enedi-amine) are stacked alternately parallel to the b

SUBMITTER: Matsushita N 

PROVIDER: S-EPMC6281129 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature