Ontology highlight
ABSTRACT:
SUBMITTER: Li YZ
PROVIDER: S-EPMC6289101 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
Chemical science 20180917 46
Monostibine-protected ionic Au<sub>13</sub> nanoclusters, namely, [Au<sub>13</sub>(L)<sub>8</sub>(Cl)<sub>4</sub>][Cl] (L= SbPh<sub>3</sub>, <b>2a</b>·Cl; Sb(<i>p</i>-tolyl)<sub>3</sub>, <b>2b</b>·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH<sub>4</sub> in dichloromethane. Anion exchange with <b>2a</b>·Cl afforded [Au<sub>13</sub>(SbPh<sub>3</sub>)<sub>8</sub>(Cl)<sub>4</sub>][X] (X = PF<sub>6</sub>, <b>2a</b>·PF<sub>6</sub>; BPh<sub>4</sub>, <b>2a</b>·BPh<sub>4</sub>). All the ...[more]