Ontology highlight
ABSTRACT:
SUBMITTER: Liu Q
PROVIDER: S-EPMC6289102 | biostudies-literature | 2018 Dec
REPOSITORIES: biostudies-literature
Liu Qianyi Q Sun Beiqi B Liu Zheng Z Kao Yi Y Dong Bo-Wei BW Jiang Shang-Da SD Li Feng F Liu Guoquan G Yang Yang Y Mo Fanyang F
Chemical science 20180917 46
Herein we report a general electrochemical strategy for the Sandmeyer reaction. Using electricity as the driving force, this protocol employs a simple and inexpensive halogen source, such as NBS, CBrCl<sub>3</sub>, CH<sub>2</sub>I<sub>2</sub>, CCl<sub>4</sub>, LiCl and NaBr for the halogenation of aryl diazonium salts. In addition, we found that these electrochemical reactions could be performed using anilines as the starting material in a one-pot fashion. Furthermore, the practicality of this p ...[more]