Ontology highlight
ABSTRACT:
SUBMITTER: Duong TD
PROVIDER: S-EPMC6301758 | biostudies-literature | 2018 Nov
REPOSITORIES: biostudies-literature
Duong Thien D TD Sapchenko Sergey A SA da Silva Ivan I Godfrey Harry G W HGW Cheng Yongqiang Y Daemen Luke L LL Manuel Pascal P Ramirez-Cuesta Anibal J AJ Yang Sihai S Schröder Martin M
Journal of the American Chemical Society 20181113 47
We report the first example of crystallographic observation of acetylene binding to -NO<sub>2</sub> groups in a metal-organic framework (MOF). Functionalization of MFM-102 with -NO<sub>2</sub> groups on phenyl groups leads to a 15% reduction in BET surface area in MFM-102-NO<sub>2</sub>. However, this is coupled to a 28% increase in acetylene adsorption to 192 cm<sup>3</sup> g<sup>-1</sup> at 298 K and 1 bar, comparable to other leading porous materials. Neutron diffraction and inelastic scatter ...[more]