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Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal-Organic Framework.

ABSTRACT: We report a record-high SO2 adsorption capacity of 12.3 mmol g-1 in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO2 adsorption in MFM-601 is fully reversible and highly selective over CO2 and N2. The binding domains for adsorbed SO2 and CO2 molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high selectivity.

SUBMITTER: Carter JH 

PROVIDER: S-EPMC6301759 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature

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Exceptional Adsorption and Binding of Sulfur Dioxide in a Robust Zirconium-Based Metal-Organic Framework.

Carter Joseph H JH   Han Xue X   Moreau Florian Y FY   da Silva Ivan I   Nevin Adam A   Godfrey Harry G W HGW   Tang Chiu C CC   Yang Sihai S   Schröder Martin M  

Journal of the American Chemical Society 20181112 46

We report a record-high SO<sub>2</sub> adsorption capacity of 12.3 mmol g<sup>-1</sup> in a robust porous material, MFM-601, at 298 K and 1.0 bar. SO<sub>2</sub> adsorption in MFM-601 is fully reversible and highly selective over CO<sub>2</sub> and N<sub>2</sub>. The binding domains for adsorbed SO<sub>2</sub> and CO<sub>2</sub> molecules in MFM-601 have been determined by in situ synchrotron X-ray diffraction experiments, giving insights at the molecular level to the basis of the observed high  ...[more]

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