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Synthesis and Stereochemical Assignment of Arenolide.

ABSTRACT: The convergent synthesis of candidate stereoisomers of the natural product arenolide was accomplished using recently developed catalytic boron-based reactions. Comparison of the spectral data for candidate structures with that reported for the authentic natural product revealed the likely stereostructure of the natural compound.

SUBMITTER: Liu X 

PROVIDER: S-EPMC6313251 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature

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Synthesis and Stereochemical Assignment of Arenolide.

Liu Xun X   Sun Chunrui C   Mlynarski Scott S   Morken James P JP  

Organic letters 20180322 7

The convergent synthesis of candidate stereoisomers of the natural product arenolide was accomplished using recently developed catalytic boron-based reactions. Comparison of the spectral data for candidate structures with that reported for the authentic natural product revealed the likely stereostructure of the natural compound. ...[more]

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