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Creation of Superhydrophobic and Superhydrophilic Surfaces on ABS Employing a Nanosecond Laser.

ABSTRACT: A nanosecond green laser was employed to obtain both superhydrophobic and superhydrophilic surfaces on a white commercial acrylonitrile-butadiene-styrene copolymer (ABS). These wetting behaviors were directly related to a laser-induced superficial modification. A predefined pattern was not produced by the laser, rather, the entire surface was covered with laser pulses at 1200 DPI by placing the sample at different positions along the focal axis. The changes were related to the laser fluence used in each case. The highest fluence, on the focal position, induced a drastic heating of the material surface, and this enabled the melted material to flow, thus leading to an almost flat superhydrophilic surface. By contrast, the use of a lower fluence by placing the sample 0.8 µm out of the focal position led to a poor material flow and a fast cooling that froze in a rugged superhydrophobic surface. Contact angles higher than 150° and roll angles of less than 10° were obtained. These wetting behaviors were stable over time.

SUBMITTER: Lavieja C

PROVIDER: S-EPMC6316655 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature

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Creation of Superhydrophobic and Superhydrophilic Surfaces on ABS Employing a Nanosecond Laser.

Lavieja Cristian C Oriol Luis L Peña José-Ignacio JI

Materials (Basel, Switzerland) 20181214 12

A nanosecond green laser was employed to obtain both superhydrophobic and superhydrophilic surfaces on a white commercial acrylonitrile-butadiene-styrene copolymer (ABS). These wetting behaviors were directly related to a laser-induced superficial modification. A predefined pattern was not produced by the laser, rather, the entire surface was covered with laser pulses at 1200 DPI by placing the sample at different positions along the focal axis. The changes were related to the laser fluence used ...[more]

PMID: 30558144

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Project description:Laser-textured surfaces enabling reversible wettability switching and improved optical properties are gaining importance in cutting-edge applications, including self-cleaning interfaces, tunable optical lenses, microfluidics, and lab-on-chip systems. Fabrication of such surfaces by combining nanosecond-laser texturing and low-temperature annealing of titanium Ti-6Al-4V alloy was demonstrated by Lian et al. in ACS Appl. Mater. Inter. 2020, 12 (5), 6573-6580. However, it is difficult to agree with (i) their contradictory explanation of the wettability transition due to low-temperature annealing and (ii) their theoretical description of the optical behavior of the laser-textured titanium surface. This comment provides an alternative view-supported by both experimental results and theoretical investigation-on how the results by Lian et al. could be interpreted more correctly. The annealing experiments clarify that controlled contamination is crucial in obtaining consistent surface wettability alterations after low-temperature annealing. Annealing of laser-textured titanium at 100 °C in contaminated and contaminant-free furnaces leads to completely different wettability transitions. Analysis of the surface chemistry by XPS and ToF-SIMS reveals that (usually overlooked) contamination with hydrophobic polydimethylsiloxane (PDMS) may arise from the silicone components of the furnace. In this case, a homogeneous thin PDMS film over the entire surface results in water repellency (contact angle of 161° and roll-off angle of 15°). In contrast, annealing under the same conditions but in a contaminant-free furnace preserves the initial superhydrophilicity, whereas the annealing at 350 °C turns the hydrophobicity "off". The theoretical calculations of optical properties demonstrate that the laser-induced oxide layer formed during the laser texturing significantly influences the surface optical behavior. Consequently, the interference of light reflected by the air-oxide and the oxide-metal interfaces should not be neglected and enables several advanced approaches to exploit such optical properties.

Dataset Information

Creation of Superhydrophobic and Superhydrophilic Surfaces on ABS Employing a Nanosecond Laser.

Publications

Creation of Superhydrophobic and Superhydrophilic Surfaces on ABS Employing a Nanosecond Laser.

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