Ontology highlight
ABSTRACT:
SUBMITTER: Moran-Ruiz A
PROVIDER: S-EPMC6327175 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Morán-Ruiz Aroa A Wain-Martin Aritza A Orera Alodia A Sanjuán María Luisa ML Larrañaga Aitor A Slater Peter R PR Arriortua Maribel M
IUCrJ 20190101 Pt 1
The first fluorination of the cuspidine-related phases of Ln<sub>4</sub>(Al<sub>2</sub>O<sub>7</sub>□)O<sub>2</sub> (where Ln = Sm, Eu, Gd) is reported. A low-temperature reaction with poly(vinyl-idene difluoride) lead to the fluorine being substituted in place of oxygen and inserted into the vacant position between the dialuminate groups. X-ray photoelectron spectroscopy shows the presence of the F 1<i>s</i> photoelectron together with an increase in Al 2<i>p</i> and rare-earth 4<i>d</i> bindin ...[more]