Ontology highlight
ABSTRACT:
SUBMITTER: Barwa E
PROVIDER: S-EPMC6331139 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Barwa Erik E Ončák Milan M Pascher Tobias F TF Taxer Thomas T van der Linde Christian C Beyer Martin K MK
The journal of physical chemistry. A 20181219 1
Hydrated singly charged metal ions doped with carbon dioxide, Mg<sup>2+</sup>(CO<sub>2</sub>)<sup>-</sup>(H<sub>2</sub>O) <sub>n</sub>, in the gas phase are valuable model systems for the electrochemical activation of CO<sub>2</sub>. Here, we study these systems by Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry combined with ab initio calculations. We show that the exchange reaction of CO<sub>2</sub> with O<sub>2</sub> proceeds fast with bare Mg<sup>+</sup>(CO<sub>2</sub>), ...[more]