Ontology highlight
ABSTRACT:
SUBMITTER: Liu D
PROVIDER: S-EPMC6345588 | biostudies-literature | 2018 Oct
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20181004 43
The double- or triple-decker 3D metallo-hexagons were obtained by self-assembly of multitopic tris-terpyridines with Cd<sup>2+</sup> ions in near-quantitative yield. Comprising up to 72 ionic pairs, the multiple spoked wheels display characteristic reversible gelation properties under thermodynamic conditions. The supramolecular metallo-nanoarchitectures were characterized by <sup>1</sup> H NMR, 2D NMR (COSY and NOESY), and diffusion-ordered spectroscopy (DOSY) and HR-ESI-MS, traveling-wave ion ...[more]