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A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones.


ABSTRACT: The dinuclear ruthenium complex [Ru2H(?-H)(Me2dad)(dbcot)2] contains a 1,4-dimethyl-diazabuta-1,3-diene (Me2dad) as a non-innocent bridging ligand between the metal centers to give a [Ru2(Me2dad)] core. In addition, each ruthenium is bound to one dibenzo[a,e]cyclooctatetraene (dbcot) ligand. This Ru dimer converts H2 to protons and electrons. It also catalyzes reversibly under mild conditions the selective hydrogenation of vitamins K2 and K3 to their corresponding hydroquinone equivalents without affecting the C[double bond, length as m-dash]C double bonds. Mechanistic studies suggest that the [Ru2(Me2dad)] moiety, like hydrogenases, reacts with H2 and releases electrons and protons stepwise.

SUBMITTER: Yang X 

PROVIDER: S-EPMC6346631 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature

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A low-valent dinuclear ruthenium diazadiene complex catalyzes the oxidation of dihydrogen and reversible hydrogenation of quinones.

Yang Xiuxiu X   Gianetti Thomas L TL   Wörle Michael D MD   van Leest Nicolaas P NP   de Bruin Bas B   Grützmacher Hansjörg H  

Chemical science 20181115 4


The dinuclear ruthenium complex [Ru<sub>2</sub>H(μ-H)(Me<sub>2</sub>dad)(dbcot)<sub>2</sub>] contains a 1,4-dimethyl-diazabuta-1,3-diene (Me<sub>2</sub>dad) as a non-innocent bridging ligand between the metal centers to give a [Ru<sub>2</sub>(Me<sub>2</sub>dad)] core. In addition, each ruthenium is bound to one dibenzo[<i>a</i>,<i>e</i>]cyclooctatetraene (dbcot) ligand. This Ru dimer converts H<sub>2</sub> to protons and electrons. It also catalyzes reversibly under mild conditions the selective  ...[more]

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