Ontology highlight
ABSTRACT:
SUBMITTER: Yang X
PROVIDER: S-EPMC6346631 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Yang Xiuxiu X Gianetti Thomas L TL Wörle Michael D MD van Leest Nicolaas P NP de Bruin Bas B Grützmacher Hansjörg H
Chemical science 20181115 4
The dinuclear ruthenium complex [Ru<sub>2</sub>H(μ-H)(Me<sub>2</sub>dad)(dbcot)<sub>2</sub>] contains a 1,4-dimethyl-diazabuta-1,3-diene (Me<sub>2</sub>dad) as a non-innocent bridging ligand between the metal centers to give a [Ru<sub>2</sub>(Me<sub>2</sub>dad)] core. In addition, each ruthenium is bound to one dibenzo[<i>a</i>,<i>e</i>]cyclooctatetraene (dbcot) ligand. This Ru dimer converts H<sub>2</sub> to protons and electrons. It also catalyzes reversibly under mild conditions the selective ...[more]