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Iron-decorated nitrogen-rich carbons as efficient oxygen reduction electrocatalysts for Zn-air batteries.

ABSTRACT: A low-cost and scalable method has been developed to synthesize Fe-decorated N-rich carbon electrocatalysts for the oxygen reduction reaction (ORR) based on pyrolysis of metal carbonyls containing metal-organic frameworks (MOFs). Such a method simultaneously optimizes the Fe-related active sites and the porous structure of the catalysts. Accordingly, the best-performing Fe-NC-900-M catalyst shows excellent ORR activity with a half-wave potential of 0.91 V vs. RHE, exceeding that of the 40% Pt/C catalyst in alkaline media. Furthermore, the zinc-air batteries constructed with Fe-NC-900-M as the cathode catalyst exhibit high open-circuit voltage (1.5 V) and peak power density (271 mW cm-2), and outperform most zinc-air batteries with noble-metal free ORR catalysts.

SUBMITTER: Liu Z

PROVIDER: S-EPMC6348107 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Iron-decorated nitrogen-rich carbons as efficient oxygen reduction electrocatalysts for Zn-air batteries.

Liu Zhuang Z Liu Jing J Wu Hao Bin HB Shen Gurong G Le Zaiyuan Z Chen Gen G Lu Yunfeng Y

Nanoscale 20180901 36

A low-cost and scalable method has been developed to synthesize Fe-decorated N-rich carbon electrocatalysts for the oxygen reduction reaction (ORR) based on pyrolysis of metal carbonyls containing metal-organic frameworks (MOFs). Such a method simultaneously optimizes the Fe-related active sites and the porous structure of the catalysts. Accordingly, the best-performing Fe-NC-900-M catalyst shows excellent ORR activity with a half-wave potential of 0.91 V vs. RHE, exceeding that of the 40% Pt/C ...[more]

PMID: 30183045

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