Macromolecules with programmable shape, size, and chemistry.
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ABSTRACT:
SUBMITTER: Walsh DJ
PROVIDER: S-EPMC6358684 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Publications
Macromolecules with programmable shape, size, and chemistry.
Walsh Dylan J DJ Guironnet Damien D
Proceedings of the National Academy of Sciences of the United States of America 20190117 5
Shape, size, and composition are the most fundamental design features, enabling highly complex functionalities. Despite recent advances, the independent control of shape, size, and chemistry of macromolecules remains a synthetic challenge. We report a scalable methodology to produce large, well-defined macromolecules with programmable shape, size, and chemistry that combines reactor engineering principles and controlled polymerizations. Specifically, bottlebrush polymers with conical, ellipsoida ...[more]
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