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Diffusion Control of Organic Cathode Materials in Lithium Metal Battery.

ABSTRACT: Organic cathode materials for lithium batteries are becoming increasingly popular because they have high theoretical redox voltage, high gravimetric capacity, low cost, easy processing and sustainability. However, their development is limited by their solubility in the electrolyte, which leads to rapid deterioration of the battery upon cycling. We developed a Janus membrane, which consists of two layers - a commercial polypropylene separator (Celgard) and a 300-600?nm layer of exfoliated graphite that was applied by a simple and environmentally friendly process. The submicron graphite layer is only permeable to Li+ and it drastically improves the battery performance, as measured by capacity retention and high coulombic efficiency, even at 2C rates. Post-mortem analysis of the battery indicates that the new membrane protects the anode against corrosion, and cathode dissolution is reduced. This graphite-based membrane is expected to greatly expedite the deployment of batteries with organic cathodes.

SUBMITTER: Belanger RL

PROVIDER: S-EPMC6362235 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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