Expanding the Spectrum of Light-Driven Peroxygenase Reactions.
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ABSTRACT:
SUBMITTER: Willot SJ
PROVIDER: S-EPMC6369655 | biostudies-literature | 2019 Feb
REPOSITORIES: biostudies-literature
Publications
Expanding the Spectrum of Light-Driven Peroxygenase Reactions.
Willot Sébastien J-P SJ Fernández-Fueyo Elena E Tieves Florian F Pesic Milja M Alcalde Miguel M Arends Isabel W C E IWCE Park Chan Beum CB Hollmann Frank F
ACS catalysis 20181218 2
Peroxygenases require a controlled supply of H<sub>2</sub>O<sub>2</sub> to operate efficiently. Here, we propose a photocatalytic system for the reductive activation of ambient O<sub>2</sub> to produce H<sub>2</sub>O<sub>2</sub> which uses the energy provided by visible light more efficiently based on the combination of wavelength-complementary photosensitizers. This approach was coupled to an enzymatic system to make formate available as a sacrificial electron donor. The scope and current limit ...[more]
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