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Air-Curable, High-Resolution Patternable Oxetane-Based Liquid Crystalline Photonic Films via Flexographic Printing.


ABSTRACT: The production of patterned photonic films on a large scale remains a challenge. Here, we report on a new class of photonic materials that are based on oxetane liquid crystals (LCs). Patterned reflective coatings can be produced from these materials on flexible substrates by using flexographic printing. This industrially relevant process allows for upscaling in future applications. Furthermore, the oxetane LCs used do not require an inert atmosphere for photopolymerization, unlike previously described acrylate systems. We show that the flexographic printing process results in excellent alignment, and that the patterns produced display a high resolution. Additionally, we demonstrate that free-standing photonic reflecting foils can also be produced from these materials. Our new oxetane-based patterned iridescent colored materials have potential application for both esthetic purposes as well as anticounterfeit labels.

SUBMITTER: Hoekstra DC 

PROVIDER: S-EPMC6385056 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature

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Air-Curable, High-Resolution Patternable Oxetane-Based Liquid Crystalline Photonic Films via Flexographic Printing.

Hoekstra Davey C DC   Nickmans Koen K   Lub Johan J   Debije Michael G MG   Schenning Albert P H J APHJ  

ACS applied materials & interfaces 20190208 7


The production of patterned photonic films on a large scale remains a challenge. Here, we report on a new class of photonic materials that are based on oxetane liquid crystals (LCs). Patterned reflective coatings can be produced from these materials on flexible substrates by using flexographic printing. This industrially relevant process allows for upscaling in future applications. Furthermore, the oxetane LCs used do not require an inert atmosphere for photopolymerization, unlike previously des  ...[more]

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