Ontology highlight
ABSTRACT:
SUBMITTER: Lu C
PROVIDER: S-EPMC6385593 | biostudies-literature | 2018 Jun
REPOSITORIES: biostudies-literature
Lu Chenjie C Zhang Mingming M Tang Danting D Yan Xuzhou X Zhang ZeYuan Z Zhou Zhixuan Z Song Bo B Wang Heng H Li Xiaopeng X Yin Shouchun S Sepehrpour Hajar H Stang Peter J PJ
Journal of the American Chemical Society 20180612 24
Herein, we report the preparation of a multifunctional metallacage-core supramolecular gel by orthogonal metal coordination and host-guest interactions. A tetragonal prismatic cage with four appended 21-crown-7 (21C7) moieties in its pillar parts was first prepared via the metal-coordination-driven self-assembly of cis-Pt(PEt<sub>3</sub>)<sub>2</sub>(OTf)<sub>2</sub>, tetraphenylethene (TPE)-based sodium benzoate ligands and linear dipyridyl ligands. Further addition of a bisammonium linker to t ...[more]