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Ammonia Storage by Reversible Host-Guest Site Exchange in a Robust Metal-Organic Framework.

ABSTRACT: MFM-300(Al) shows reversible uptake of NH3 (15.7 mmol g-1 at 273 K and 1.0 bar) over 50 cycles with an exceptional packing density of 0.62 g cm-3 at 293 K. In situ neutron powder diffraction and synchrotron FTIR micro-spectroscopy on ND3 @MFM-300(Al) confirms reversible H/D site exchange between the adsorbent and adsorbate, representing a new type of adsorption interaction.

SUBMITTER: Godfrey HGW 

PROVIDER: S-EPMC6391960 | biostudies-literature |

REPOSITORIES: biostudies-literature

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