Ontology highlight
ABSTRACT:
SUBMITTER: Danielson AP
PROVIDER: S-EPMC6403633 | biostudies-literature | 2018 Jul
REPOSITORIES: biostudies-literature
Danielson Alex P AP Van-Kuren Dylan Bailey DB Bornstein Joshua P JP Kozuszek Caleb T CT Berberich Jason A JA Page Richard C RC Konkolewicz Dominik D
Polymers 20180705 7
A detailed mechanistic and kinetic study of enzymatically initiated RAFT polymerization is performed by combining enzymatic assays and polymerization kinetics analysis. Horseradish peroxidase (HRP) initiated RAFT polymerization of dimethylacrylamide (DMAm) was studied. This polymerization was controlled by 2-(propionic acid)ylethyl trithiocarbonate (PAETC) in the presence of H₂O₂ as a substrate and acetylacetone (ACAC) as a mediator. In general, well controlled polymers with narrow molecular wei ...[more]