Dataset Information

Phase Separation Driven On-Demand Debondable Waterborne Pressure-Sensitive Adhesives.

ABSTRACT: A waterborne pressure-sensitive adhesive (PSA) that shows high adhesive performance and easy debondability on demand without leaving residues on the substrate (adhesive failure) has been developed. A key component of the PSA is a semicrystalline phase that is beneficial for the adhesive properties and that becomes fluid when heated above the melting temperature. Migration of this liquid-like polymer to the substrate-adhesive interface and hardening upon cooling results in a hard non-tacky interface that facilitates debonding. The effect of the particle morphology on the debonding ability is discussed.

SUBMITTER: Mehravar E

PROVIDER: S-EPMC6403930 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Publications

Phase Separation Driven On-Demand Debondable Waterborne Pressure-Sensitive Adhesives.

Mehravar Ehsan E Gross Michael A MA Leal Gracia Patricia GP Reck Bernd B Leiza Jose R JR Asua José M JM

Polymers 20180902 9

A waterborne pressure-sensitive adhesive (PSA) that shows high adhesive performance and easy debondability on demand without leaving residues on the substrate (adhesive failure) has been developed. A key component of the PSA is a semicrystalline phase that is beneficial for the adhesive properties and that becomes fluid when heated above the melting temperature. Migration of this liquid-like polymer to the substrate-adhesive interface and hardening upon cooling results in a hard non-tacky interf ...[more]

PMID: 30960900

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Project description:Pressure-sensitive adhesives (PSAs) are usually made from viscoelastic, high-molecular-weight copolymers, which are fine-tuned by adjusting the comonomer ratios, molecular weights, and cross-link densities to optimize the adhesion properties for the desired end-use. To create a lightly cross-linked network, an ultraviolet (UV) photoinitiator can be incorporated. Here, we present the first use of perfluorophenylazide chemistry to control precisely a polyacrylate network for application as a PSA. Upon UV irradiation, the highly reactive nitrene from the azide moiety reacts with nearby molecules through a C-H insertion reaction, resulting in cross-linking via covalent bonding. This approach offers three benefits: (1) a means to optimize adhesive properties without the addition of an external photoinitiator; (2) the ability to switch off the tack adhesion on demand via a high cross-linking density; and (3) a platform for additional chemical modification. A series of poly(n-butyl acrylate-co-2,3,4,5,6-pentafluorobenzyl acrylate) or poly(PFBA-co-BA) copolymers were synthesized and modified post-polymerization into the photo-reactive poly(n-butyl acrylate-co-4-azido-2,3,5,6-tetrafluorobenzyl acrylate) [azide-modified poly(PFBA-co-BA)] with various molar contents. When cast into films, the azide-modified copolymers with a high azide content achieved a very high shear resistance after UV irradiation, whereas the tack and peel adhesion decreased strongly with the increase in azide content, indicating that excessive cross-linking occurred. These materials are thus photo-switchable. However, in the low range of azide content, an optimum probe tack adhesion energy was obtained in films with a 0.3 mol % azide content, where a long stress plateau (indicating good fibrillation) with a high plateau stress was observed. An optimum peel adhesion strength was achieved with 0.5 mol % azide. Thus, the adhesion was finely controlled by the degree of cross-linking of the PSA, as determined by the azide content of the copolymer chain. Finally, as a demonstration of the versatility and advantages of the material platform, we show an azide-aldehyde-amine multicomponent modification of the azide copolymer to make a dye-functionalized film that retains its adhesive properties. This first demonstration of using azide functionality has enormous potential for functional PSA design.

Dataset Information

Phase Separation Driven On-Demand Debondable Waterborne Pressure-Sensitive Adhesives.

Publications

Phase Separation Driven On-Demand Debondable Waterborne Pressure-Sensitive Adhesives.

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