Proposal of a rhombohedral-tetragonal phase composition for maximizing piezoelectricity of (K,Na)NbO₃ ceramics.

ABSTRACT: Great progress in the field of piezoelectricity of (K,Na)NbO₃ (KNN) lead-free ceramics, driven by emerging rhombohedral-tetragonal (R-T) phase boundary, has instigated research activity regarding elaborate controls of the phase boundary structure. Through phase-microstructure-property mapping in KNN ceramics doped with Bi-containing perovskite oxides, in this study we for the first time report the existence of a certain R-T phase boundary state by which to create maximum piezoelectric response in KNN systems. This phase boundary condition is usually comprised of approximately 15% R phase and 85% T phase, regardless of the choice of dopant material. Any deviation from this phase composition, either by inclusion of orthorhombic (O) phase or by enrichment of R phase, has a negative

SUBMITTER: Lee MK 

PROVIDER: S-EPMC6414638 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature