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Catalyst System for Hydrogenation Catalysis Based on Multiarm Hyperbranched Polymer Templated Metal (Au, Pt, Pd, Cu) Nanoparticles.

ABSTRACT: With a hyperbranched poly(amidoamine) core and many water-soluble poly(ethylene glycol) monomethyl ether arms connected by pH-sensitive acylhydrazone bonds, multiarm hyperbranched polymer was used as nanoreactor and reductant to prepare metal nanoparticles endowed with intelligence and biocompatibility. The multiarm hyperbranched polymer encapsulated nanoparticles (NPs) showed excellent catalytic activity for hydrogenation, thus an excellent catalyst system for hydrogenation was established. The rate constants could reach as high as 3.48 L·s^-1·m^-2, which can be attributed to the lack of surface passivation afforded by the multiarm hyperbranched polymer.

SUBMITTER: Shi Y

PROVIDER: S-EPMC6418630 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature

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Catalyst System for Hydrogenation Catalysis Based on Multiarm Hyperbranched Polymer Templated Metal (Au, Pt, Pd, Cu) Nanoparticles.

Shi Yunfeng Y Liu Lixin L Zhang Fengyue F Niu Mengyuan M Zhao Yanzhu Y Fan Yifan Y Liang Yanping Y Liu Mei M Zhang Zhenzhu Z Wang Junjie J

Polymers 20170919 9

With a hyperbranched poly(amidoamine) core and many water-soluble poly(ethylene glycol) monomethyl ether arms connected by pH-sensitive acylhydrazone bonds, multiarm hyperbranched polymer was used as nanoreactor and reductant to prepare metal nanoparticles endowed with intelligence and biocompatibility. The multiarm hyperbranched polymer encapsulated nanoparticles (NPs) showed excellent catalytic activity for hydrogenation, thus an excellent catalyst system for hydrogenation was established. The ...[more]

PMID: 30965762

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