Dataset Information

Geochemical characteristics of dissolved heavy metals in Zhujiang River, Southwest China: spatial-temporal distribution, source, export flux estimation, and a water quality assessment.

ABSTRACT: To investigate the sources and spatial-temporal distribution of dissolved heavy metals in river water, and to evaluate the water quality, a total of 162 water samples were collected from 81 key sampling points in high and low flow seasons separately in the Zhujiang River, Southwest China. Ten dissolved heavy metals (V, Cr, Mn, Co, Ni, Cu, Mo, Cd, Ba, and Pb) in the Zhujiang River water exhibit little variation at temporal scale, but vary with a significant spatial heterogeneity. Furthermore, different metals present different variation trends along the main channel of the Zhujiang River. Our results suggest that Ba (14.72 ?g L-1 in low flow season and 12.50 ?g L-1 in high flow season) and Cr (6.85 ?g L-1 in low flow season and 7.52 ?g L-1 in high flow season) are consistently the most abundant metals in the two sampling periods. According to the water quality index (WQI values ranged from 1.3 to 43.9) and health risk assessment, metals investigated in Zhujiang River are below the hazard level (all hazard index (HI) < 1). Application of statistical approaches, including correlation matrix and principal component analysis (PCA), identify three principal components that account for 61.74% of the total variance, the results conclude that the anthropogenic heavy metals (V, Cr, Ni, and Cu) are greatly impacted by the dilution effect, and the heavy metals in Zhujiang River are mainly presented a natural sources signature from the perspective of entire basin. Moreover, our results reveal that the estimated export budget of several heavy metals including V (735.6 t year-1), Cr (1,561.1 t year-1), Ni (498.2 t year-1), and Mo (118.9 t year-1) to the ocean are higher than the world average.

SUBMITTER: Zeng J

PROVIDER: S-EPMC6420802 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature

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Geochemical characteristics of dissolved heavy metals in Zhujiang River, Southwest China: spatial-temporal distribution, source, export flux estimation, and a water quality assessment.

Zeng Jie J Han Guilin G Wu Qixin Q Tang Yang Y

PeerJ 20190313

To investigate the sources and spatial-temporal distribution of dissolved heavy metals in river water, and to evaluate the water quality, a total of 162 water samples were collected from 81 key sampling points in high and low flow seasons separately in the Zhujiang River, Southwest China. Ten dissolved heavy metals (V, Cr, Mn, Co, Ni, Cu, Mo, Cd, Ba, and Pb) in the Zhujiang River water exhibit little variation at temporal scale, but vary with a significant spatial heterogeneity. Furthermore, dif ...[more]

PMID: 30886773

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Project description:It is necessary to establish local geochemical baseline concentrations (GBCs) due to the lack or the inapplicability of regional background values in the study area. The establishment of GBCs of heavy metal (HM) in soil helps in making the accurate assessment of pollution, and then provides a basis for pollution control. Based on this, a case study was undertaken to study the GBCs of the Jiedong District, Guangdong Province, China. In this research, cumulative frequency distribution curves were utilized to determine the local GBCs in the subsoils. The determined GBCs of Cr, Hg, As, Pb, Ni, Cd, Cu, Zn, Co and V were 39.91, 0.072, 11.48, 47.62, 12.70, 0.17, 14.22, 64.54, 6.31, and 68.14 mg/kg, respectively. The average concentrations of Hg, As, Pb, Cd, Cu and Zn in the topsoils exceeded the corresponding baseline concentrations. In particular, the contents of Cd and Hg were 1.53 and 2.22 times higher than GBCs. According to this baseline criterion, enrichment factor (EF), pollution load index (PLI) and ecological risk index (RI) were applied to assessing HM pollution. EF and PLI suggested that most areas were under moderate contamination, while Hg and Cd pollution was more serious. And the RI values presented that the potential ecological risks were low in most parts of the study area. The possible origins of HMs were identified by combining positive matrix factorization with EF and geostatistics. Comprehensive analysis indicated that Hg and Cd were related to industrial activities, such as textile and garment processing, plastic and rubber production and metal manufacturing. Arsenic and part of Cu mainly came from agricultural activities, namely the use of pesticides, fertilizers and livestock manures. Lead and Zn were mainly attributed to traffic emissions. Chromium, Ni, V, Co, and part of Cu were originated from natural source controlled by parent materials. The corresponding contributions of these sources were 20.61%, 24.20%, 19.22% and 35.97%, respectively. This work provides information to prevent and control the soil HM pollution by proposing the efficient management of anthropogenic sources.

Project description:The anthropogenic heavy metal dissemination in the natural environment through riverine sediments is a major ecological and public health concern around the world. This study gives insight into the source apportionment and potential ecological and health risks of heavy metals in river sediments of the Urmia Lake basin, a natural world heritage located in northwestern Iran. A comprehensive sediment sampling was conducted in seven major rivers feeding the basin during the summer and winter of 2021. Samples were analyzed for zinc (Zn), copper (Cu), cadmium (Cd), lead (Pb), and nickel (Ni) contents and a suite of chemical and physical properties. Subsequently, Pollution Index (PI), Pollution Load Index (PLI), Ecological Risk (ER), Hazard Quotients (HQ), Hazard Index (HI), and Carcinogenic Risk (CR) indices were determined. The mean concentration of heavy metals in all rivers' sediments exhibited the descending order of Ni > Zn > Pb > Cu > Cd during both summer and winter. Multivariate analysis suggested that Zn was primarily initiated from natural processes, Cd and Pb were affected by human activities, and Cu along Ni were derived from natural and anthropogenic factors. The PI unveiled that most sediment samples were unpolluted to slightly polluted by Zn, Cu, and Pb, and slightly to moderately polluted by Cd. PLI and ER indices demonstrated that the sediment poses non to moderate pollution and low to moderate ecological risk, respectively. Using a human health risk approach, we found that the HI values of all heavy metals and THI were less than one for children and adults implying non-carcinogenic risk in the analyzed sediments. Carcinogenic effects of Cd and Pb at all rivers sediments via ingestion, inhalation, and dermal contact were almost within tolerable risks (1 × 10-6 to 1 × 10-4) for children and adults. PI, PLI, ER, HQ, HI, and CR index values of sediment samples during the summer were higher than those during the winter. This is attributed to the greater heavy metal concentrations and the lower water flow during summer. Our results provide practical information for better management and control of heavy metal pollution in aquatic-sedimentary ecosystems.

Dataset Information

Geochemical characteristics of dissolved heavy metals in Zhujiang River, Southwest China: spatial-temporal distribution, source, export flux estimation, and a water quality assessment.

Publications

Geochemical characteristics of dissolved heavy metals in Zhujiang River, Southwest China: spatial-temporal distribution, source, export flux estimation, and a water quality assessment.

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