Ontology highlight
ABSTRACT:
SUBMITTER: Kobayashi H
PROVIDER: S-EPMC6429599 | biostudies-literature | 2019 Mar
REPOSITORIES: biostudies-literature
Chemical science 20190206 11
We report the synthesis and characterization of highly active Cu nanoparticles covered with zirconium/hafnium-based metal-organic frameworks for CO<sub>2</sub> hydrogenation to methanol. Compared to <b>Cu/γ-Al<sub>2</sub>O<sub>3</sub></b> , <b>Cu/ZIF-8</b>, <b>Cu/MIL-100</b> and <b>Cu/UiO-66</b> composites, UiO-66 acts as the most active support, with <b>Cu/Zr-UiO-66</b> producing methanol at a rate 70 times higher than that of <b>Cu/γ-Al<sub>2</sub>O<sub>3</sub></b> . In addition, the replaceme ...[more]