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Direct Synthesis of Branched Carboxylic Acid Functionalized Poly(1-octene) by ?-Diimine Palladium Catalysts.

ABSTRACT: In this work, we studied propylene polymerization using some ?-diimine palladium catalysts with systematically varied ligand sterics. In propylene polymerization, the ligand steric effect exhibits significant variations on the catalytic activity, polymer molecular weight, and branching density. However, the regio control for the polymer microstructure is poor. Furthermore, copolymerization of 1-octene with the highly challenging and biorenewable comonomer acrylic acid was investigated. High copolymer molecular weights and high comonomer incorporation ratios could be achieved in this system. This study provides a novel access for the direct synthesis of branched carboxylic acid functionalized polyolefins.

SUBMITTER: Guo L

PROVIDER: S-EPMC6432235 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Direct Synthesis of Branched Carboxylic Acid Functionalized Poly(1-octene) by α-Diimine Palladium Catalysts.

Guo Lihua L Zou Chen C Dai Shengyu S Chen Changle C

Polymers 20170327 4

In this work, we studied propylene polymerization using some α-diimine palladium catalysts with systematically varied ligand sterics. In propylene polymerization, the ligand steric effect exhibits significant variations on the catalytic activity, polymer molecular weight, and branching density. However, the regio control for the polymer microstructure is poor. Furthermore, copolymerization of 1-octene with the highly challenging and biorenewable comonomer acrylic acid was investigated. High copo ...[more]

PMID: 30970801

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Synthesis of Highly Branched Polyolefins Using Phenyl Substituted α-Diimine Ni(II) Catalysts.

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| S-EPMC6432043 | biostudies-literature

Direct Synthesis of Polyethylene Thermoplastic Elastomers Using Hybrid Bulky Acenaphthene-Based α-Diimine Ni(II) Catalysts.

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Project description:Homo- and copolymers of propylene and 1-decene were synthesized by controlled chain-walking (co)polymerization using phenyl substituted α-diimine nickel complexes activated with modified methylaluminoxane (MMAO). This catalytic system was found to polymerize propylene in a living fashion to furnish high molecular weight ethylene-propylene (EP) copolymers. The copolymerizations proceeded to give high molecular weight P/1-decene copolymers with narrow molecular weight distribution (Mw/Mn ≈ 1.2), which indicated a living nature of copolymerization at room temperature. The random copolymerization results indicated the possibility of precise branched structure control, depending on the polymerization temperature and time.

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On the Use of Triarylsilanols as Catalysts for Direct Amidation of Carboxylic Acids.

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Palladium-Based Bimetallic Nanocrystal Catalysts for the Direct Synthesis of Hydrogen Peroxide.

Project description:The direct synthesis of H2 O2 from H2 and O2 is a strongly desired reaction for green processes and a promising alternative to the commercialized anthraquinone process. The design of efficient catalysts with high activity and H2 O2 selectivity is highly desirable and yet challenging. Metal dopants enhance the performance of the active phase by increasing reaction rates, stability, and/or selectivity. The identification of efficient dopants relies mostly on catalysts prepared with a random and non-uniform deposition of active and promoter phases. To study the promotional effects of metal doping on Pd catalysts, we employ colloidal, bimetallic nanocrystals (NCs) to produce catalysts in which the active and doping metals are colocalized to a fine extent. In the absence of any acid and halide promotors, PdSn and PdGa NCs supported on acid-pretreated TiO2 (PdSn/s-TiO2 , PdGa/s-TiO2 ) were highly efficient and outperformed the monometallic Pd catalyst (Pd/s-TiO2 ), whereas in the presence of an acid promotor, the overall H2 O2 productivity was also further enhanced for the Ni-, Ga-, In-, and Sn-doped catalysts with respect to Pd/s-TiO2 .

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A lariat-functionalized copper(II) diimine-dioxime complex.

Project description:The dimeric title copper(II) complex, diaqua-1kappaO,2kappaO-bis[3,9-dimethyl-6-(2-pyridylmethyl)-4,8-diazaundeca-3,8-diene-2,10-dione dioximato(1-)]-1k(4)N(2),N(4),N(8),N(10);1:2kappa(5)O(2):N(2),N(4),N(8),N(10)-dicopper(II) diperchlorate, [Cu(2)(C(17)H(24)N(5)O(2))(2)](ClO(4))(2), crystallizes with one Cu atom in a square-pyramidal environment and the other Cu atom displaying a distorted octahedral coordination. In each case, the four N atoms in the core of the ligand (two imine and two oxime N atoms) form the base of the pyramid, with a water molecule at an apex. The two parts of the dimer are linked by an interaction [2.869 (2) A] between one of the Cu atoms and one of the oxime O atoms coordinated to the second Cu atom, and also by a hydrogen bond between the apical water molecule on the second Cu atom and the pyridyl N atom from the coordination sphere of the first Cu atom. The pyridyl N atoms of the lariat arms are not coordinated to either of the Cu atoms. Thus, this potentially pentadentate ligand is only tetradentate when coordinated to Cu(II).

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| S-EPMC9449981 | biostudies-literature

Ligand Steric Effects of α-Diimine Nickel(II) and Palladium(II) Complexes in the Suzuki-Miyaura Cross-Coupling Reaction.

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| S-EPMC7513363 | biostudies-literature

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