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Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition.

ABSTRACT: Phosphor-converted white LEDs rely on combining a blue-emitting InGaN chip with yellow and red-emitting luminescent materials. The discovery of cyan-emitting (470-500?nm) phosphors is a challenge to compensate for the spectral gap and produce full-spectrum white light. Na_0.5K_0.5Li₃SiO₄:Eu²⁺ (NKLSO:Eu²⁺) phosphor was developed with impressive properties, providing cyan emission at 486?nm with a narrow full width at half maximum (FWHM) of only 20.7?nm, and good thermal stability with an integrated emission loss of only 7% at 150?°C. The ultra-narrow-band cyan emission results from the high-symmetry cation sites, leading to almost ideal cubic coordination for UCr₄C₄-type compounds. NKLSO:Eu²⁺ phosphor allows the valley between the blue and yellow emission peaks in the white LED device to be filled, and the color-rendering index can be enhanced from 86 to 95.2, suggesting great applications in full-spectrum white LEDs.

SUBMITTER: Zhao M

PROVIDER: S-EPMC6456736 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature

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Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition.

Zhao Ming M Liao Hongxu H Molokeev Maxim S MS Zhou Yayun Y Zhang Qinyuan Q Liu Quanlin Q Xia Zhiguo Z

Light, science & applications 20190410

Phosphor-converted white LEDs rely on combining a blue-emitting InGaN chip with yellow and red-emitting luminescent materials. The discovery of cyan-emitting (470-500 nm) phosphors is a challenge to compensate for the spectral gap and produce full-spectrum white light. Na0.5K0.5Li3SiO4:Eu2+ (NKLSO:Eu2+) phosphor was developed with impressive properties, providing cyan emission at 486 nm with a narrow full width at half maximum (FW ...[more]

PMID: 30992988

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Project description:Chromophores that absorb and emit in the red spectral region (600-700 nm), are water soluble, and bear a bioconjugatable tether are relatively rare yet would fulfill many applications in photochemistry and photomedicine. Here, three molecular designs have been developed wherein stable synthetic chlorins - analogues of chlorophylls - have been tailored with PEG groups for use in aqueous solution. The designs differ with regard to order of the installation (pre/post-formation of the chlorin macrocycle) and position of the PEG groups. Six PEGylated synthetic chlorins (three free bases, three zinc chelates) have been prepared, of which four are equipped with a bioconjugatable (carboxylic acid) tether. The most effective design for aqueous solubilization entails facial encumbrance where PEG groups project above and below the plane of the hydrophobic disk-like chlorin macrocycle. The chlorins possess strong absorption at ~400 nm (B band) and in the red region (Qy band); regardless of wavelength of excitation, emission occurs in the red region. Excitation in the ~400 nm region thus provides an effective Stokes shift of >200 nm. The four bioconjugatable water-soluble chlorins exhibit Qy absorption/emission in water at 613/614, 636/638, 698/700 and 706/710 nm. The spectral properties are essentially unchanged in DMF and water for the facially encumbered chlorins, which also exhibit narrow Qy absorption and emission bands (full-width-at-half maximum of each <25 nm). The water-solubility was assessed by absorption spectroscopy over the concentration range ~0.4 ?M - 0.4 mM. One chlorin was conjugated to a mouse polyclonal IgG antibody for use in flow cytometry with compensation beads for proof-of-principle. The conjugate displayed a sharp signal when excited by a violet laser (405 nm) with emission in the 620-660 nm range. Taken together, the designs described herein augur well for development of a set of spectrally distinct chlorins with relatively sharp bands in the red region.

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Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition.

Publications

Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition.

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