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Crisscrossing coordination networks: ligand doping to control the chemomechanical properties of stimuli-responsive metallogels.

ABSTRACT: Metallogels respond to external stimuli by changing their mechanical properties. To gain a fine control over this phase-shifting event, we have designed and introduced intentional structural mismatches into the otherwise tightly knit metal-organic networks. Built using biphenolate-derived multidirectional/multidentate ligands, these soft materials display markedly different rheological properties depending on the level of "ligand doping", as well as the type of metal ion serving as a key structural support. A zinc metallogel optimized through this process responds to acids, both in the gas stream and liquid phase, by a rapid gel-sol transition and visually discernible colour change.

SUBMITTER: Kim J

PROVIDER: S-EPMC6461021 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Crisscrossing coordination networks: ligand doping to control the chemomechanical properties of stimuli-responsive metallogels.

Kim Junghwan J Lee Dongwhan D

Chemical science 20190225 13

Metallogels respond to external stimuli by changing their mechanical properties. To gain a fine control over this phase-shifting event, we have designed and introduced intentional structural mismatches into the otherwise tightly knit metal-organic networks. Built using biphenolate-derived multidirectional/multidentate ligands, these soft materials display markedly different rheological properties depending on the level of "ligand doping", as well as the type of metal ion serving as a key structu ...[more]

PMID: 31015928

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