Dataset Information

Liquid Crystals Comprising ?-Electronic Ions from Porphyrin-AuIII Complexes.

ABSTRACT: Porphyrin-AuIII complexes were found to act as ?-electronic cations, which can combine with various counteranions, including ?-electronic anions. Single-crystal X-ray analyses revealed the formation of assemblies with contributions of charge-by-charge and charge-segregated assemblies, depending on the geometry and electronic state of the counteranions. Porphyrin-AuIII complexes possessing aliphatic alkyl chains formed dimension-controlled ion-pairing assemblies as thermotropic liquid crystals, whose ionic components were highly organized by ?-? stacking and electrostatic interactions.

SUBMITTER: Haketa Y

PROVIDER: S-EPMC6463747 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Liquid Crystals Comprising π-Electronic Ions from Porphyrin-AuIII Complexes.

Haketa Yohei Y Bando Yuya Y Sasano Yoshifumi Y Tanaka Hiroki H Yasuda Nobuhiro N Hisaki Ichiro I Maeda Hiromitsu H

iScience 20190401

Porphyrin-AuIII complexes were found to act as π-electronic cations, which can combine with various counteranions, including π-electronic anions. Single-crystal X-ray analyses revealed the formation of assemblies with contributions of charge-by-charge and charge-segregated assemblies, depending on the geometry and electronic state of the counteranions. Porphyrin-AuIII complexes possessing aliphatic alkyl chains formed dimension-controlled ion-pairing assemblies as thermotro ...[more]

PMID: 30981960

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Dataset Information

Liquid Crystals Comprising ?-Electronic Ions from Porphyrin-AuIII Complexes.

Publications

Liquid Crystals Comprising π-Electronic Ions from Porphyrin-Au<sup>III</sup> Complexes.

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