Ontology highlight
ABSTRACT:
SUBMITTER: Scattolin T
PROVIDER: S-EPMC6468269 | biostudies-literature | 2018 Sep
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20180820 38
This report widens the repertoire of emerging Pd<sup>I</sup> catalysis to carbon-heteroatom, that is, C-S bond formation. While Pd<sup>0</sup> -catalyzed protocols may suffer from the formation of poisonous sulfide-bound off-cycle intermediates and lack of selectivity, the mechanistically diverse Pd<sup>I</sup> catalysis concept circumvents these challenges and allows for C-S bond formation (S-aryl and S-alkyl) of a wide range of aryl halides. Site-selective thiolations of C-Br sites in the pres ...[more]