Ontology highlight
ABSTRACT:
SUBMITTER: Liu C
PROVIDER: S-EPMC6472436 | biostudies-literature | 2019 Apr
REPOSITORIES: biostudies-literature
Chemical science 20190311 16
Through relatively subtle changes in reaction conditions, we have been able to isolate four distinct Rh/Sn cluster compounds, [Rh@Sn<sub>10</sub>]<sup>3-</sup>, [Rh@Sn<sub>12</sub>]<sup>3-</sup>, [Rh<sub>2</sub>@Sn<sub>17</sub>]<sup>6-</sup> and [Rh<sub>3</sub>@Sn<sub>24</sub>]<sup>5-</sup>, from the reaction of K<sub>4</sub>Sn<sub>9</sub> with [(COE)<sub>2</sub>Rh(μ-Cl)]<sub>2</sub>(COE = cyclooctene). The last of these has a hitherto unknown molecular topology, an edge-fused polyhedron contain ...[more]