Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Temperature-induced amorphization in CaCO₃ at high pressure and implications for recycled CaCO₃ in subduction zones.

ABSTRACT: Calcium carbonate (CaCO₃) significantly affects the properties of upper mantle and plays a key role in deep carbon recycling. However, its phase relations above 3?GPa and 1000?K are controversial. Here we report a reversible temperature-induced aragonite-amorphization transition in CaCO₃ at 3.9-7.5?GPa and temperature above 1000?K. Amorphous CaCO₃ shares a similar structure as liquid CaCO₃ but with much larger C-O and Ca-Ca bond lengths, indicating a lower density and a mechanism of lattice collapse for the temperature-induced amorphous phase. The less dense amorphous phase compared with the liquid provides an explanation for the observed CaCO₃ melting curve overturn at about 6?GPa. Amorphous CaCO₃ is stable at subduction zone conditions and could aid the recycling of carbon to the surface.

SUBMITTER: Hou M

PROVIDER: S-EPMC6488655 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Temperature-induced amorphization in CaCO3 at high pressure and implications for recycled CaCO3 in subduction zones.

Hou Mingqiang M Zhang Qian Q Tao Renbiao R Liu Hong H Kono Yoshio Y Mao Ho-Kwang HK Yang Wenge W Chen Bin B Fei Yingwei Y

Nature communications 20190429 1

Calcium carbonate (CaCO3) significantly affects the properties of upper mantle and plays a key role in deep carbon recycling. However, its phase relations above 3 GPa and 1000 K are controversial. Here we report a reversible temperature-induced aragonite-amorphization transition in CaCO3 at 3.9-7.5 GPa and temperature above 1000 K. Amorphous CaCO3 shares a similar structure as liquid CaCO3 but with much larger C-O and Ca-Ca bond lengths, indicating a l ...[more]

PMID: 31036817

Similar Datasets

High-pressure synthesis and storage of solid organic compounds in active subduction zones.

Project description:Recent thermodynamic and experimental studies have suggested that volatile organic compounds (e.g., methane, formate, and acetate) can be produced and stabilized in subduction zones, potentially playing an important role in the deep carbon cycle. However, field evidence for the high-pressure production and storage of solid organic compounds is missing. Here, we examine forearc serpentinite clasts recovered by drilling mud volcanoes above the Mariana subduction zone. Notable correlations between carbon and iron stable-isotope signatures and fluid-mobile element (B, As and Sb) concentrations provide evidence for the percolation of slab-derived CO2-rich aqueous fluids through the forearc mantle. The presence of carbonaceous matter rich in aliphatic moieties within high-temperature clasts (>350°C) demonstrates that molecular hydrogen production associated with forearc serpentinization is an efficient mechanism for the reduction and conversion of slab-derived CO2-rich fluids into solid organic compounds. These findings emphasize the need to consider the forearc mantle as an important reservoir of organic carbon on Earth.

| S-EPMC9481122 | biostudies-literature

Rapid tremor migration and pore-pressure waves in subduction zones.

Project description:Rapid tremor migration (RTM) in subduction zones is a manifestation of complex fault-zone processes on the plate interface. Recent observations have revealed a large diversity of RTM patterns that are always associated with aseismic, shear strain at the interface. Small unstable asperities embedded in the stable shear zone are thus believed to originate tremor radiation during migration. Tectonic tremors have been recognized to occur where overpressured fluids exist. Spatial variations of fluid pressure may lead to non-linear diffusion processes with potentially large implications in tremor generation. Here, we show that pore-pressure waves are likely to exist in the plate interface, propagating with speeds and pathways similar to RTMs observed in different subduction zones including Guerrero, Mexico, where we introduce new high-resolution tremor locations and a RTM source physical model. These waves may explain the whole hierarchy of RTM patterns by producing transient reductions of the fault strength and thus secondary slip fronts triggering tremor during slow earthquakes.

| S-EPMC6057928 | biostudies-literature

A Novel High-Density Phase and Amorphization of Nitrogen-Rich 1H-Tetrazole (CH2N4) under High Pressure.

Project description:The high-pressure behaviors of nitrogen-rich 1H-tetrazole (CH2N4) have been investigated by in situ synchrotron X-ray diffraction (XRD) and Raman scattering up to 75 GPa. A first crystalline-to-crystalline phase transition is observed and identified above ~3 GPa with a large volume collapse (∼18% at 4.4 GPa) from phase I to phase II. The new phase II forms a dimer-like structure, belonging to P1 space group. Then, a crystalline-to-amorphous phase transition takes place over a large pressure range of 13.8 to 50 GPa, which is accompanied by an interphase region approaching paracrystalline state. When decompression from 75 GPa to ambient conditions, the final product keeps an irreversible amorphous state. Our ultraviolet (UV) absorption spectrum suggests the final product exhibits an increase in molecular conjugation.

| S-EPMC5316957 | biostudies-literature

Constraints from the dehydration of antigorite on high-conductivity anomalies in subduction zones.

Project description:Regions with high electrical conductivities in subduction zones have attracted a great deal of attention. Determining the exact origin of these anomalies could provide critical information about the water storage and cycling processes during subduction. Antigorite is the most important hydrous mineral within deep subduction zones. The dehydration of antigorite is believed to cause high-conductivity anomalies. To date, the effects of dehydration on the electrical conductivity of antigorite remain poorly understood. Here, we report new measurements of the electrical conductivity of both natural and hot-pressed antigorite at pressures of 4 and 3 GPa, respectively, and at temperatures reaching 1073 K. We observed significantly enhanced conductivities when the antigorite was heated to temperatures beyond its thermodynamic stability field. Sharp increases in the electrical conductivity occurred at approximately 848 and 898 K following the decomposition of antigorite to forsterite, enstatite and aqueous fluids. High electrical conductivities reaching 1 S/m can be explained by the presence of an interconnected network of conductive aqueous fluids. Based on these results for the electrical conductivity of antigorite, we conclude that high-conductivity regions associated with subduction zones can be attributed to dehydration-induced fluids and the formation of interconnected networks of aqueous fluids during the dehydration of antigorite.

| S-EPMC5714963 | biostudies-literature

Origin of arc magmatic signature: A temperature-dependent process for trace element (re)-mobilization in subduction zones.

Project description:Serpentinite is a major carrier of fluid-mobile elements in subduction zones, which influences the geochemical signature of arc magmatism (e.g. high abundances of Li, Ba, Sr, B, As, Mo and Pb). Based on results from Neoproterozoic serpentinites in the Arabian-Nubian Shield, we herein report the role of antigorite in the transportation of fluid-mobile elements (FME) and light rare earth elements (LREE) from the subducted slab to arc-related magma during subduction. The serpentinites contain two generations of antigorites: the older generation is coarse-grained, formed at a temperature range of 165-250?°C and is enriched in Li, Rb, Ba and Cs, whereas the younger generation is finer-grained, formed at higher temperature conditions (425-475?°C) and has high concentrations of B, As, Sb, Mo, Pb, Sr and LREE. Magnesite, on the other hand, remains stable at sub-arc depths beyond the stability field of both antigorites, and represents a potential reservoir of FME and LREE for deeper mantle melts. Magnesite has high FME and LREE absorbing capacity (over 50-60%) higher than serpentine phases. Temperature is the main controlling factor for stability of these minerals and therefore the release of these elements from subducted slabs into arc magmatism. As the liberation of these elements varies along the length of the slab, the resulting cross-arc geochemical variation trend can help to determine the subduction polarity of ancient arcs.

| S-EPMC6506526 | biostudies-literature

The novel high-pressure/high-temperature compound Co12P7 determined from synchrotron data.

Project description:The structural properties of cobalt phosphides were investigated at high pressures and temperatures to better understand the behavior of metal-rich phosphides in Earth and planetary inter-iors. Using single-crystal X-ray diffraction synchrotron data and a laser-heated diamond anvil cell, we discovered a new high pressure-temperature (HP-HT) cobalt phosphide, Co12P7, dodeca-cobalt hepta-phosphide, synthesized at 27 GPa and 1740 K, and at 48 GPa and 1790 K. Co12P7 adopts a structure initially proposed for Cr12P7 (space-group type P , Z =1), consisting of chains of edge-sharing CoP5 square pyramids and chains of corner-sharing CoP4 tetra-hedra. This arrangement leaves space for trigonal-prismatic channels running parallel to the c axis. Coupled disordering of metal and phospho-rus atoms has been observed in this structure for related M 12P7 (M = Cr, V) compounds, but all Co and P sites are ordered in Co12P7. All atomic sites in this crystal structure are situated on special positions. Upon decompression to ambient conditions, peak broadening and loss of reflections at high angles was observed, suggesting phase instability.

| S-EPMC7534243 | biostudies-literature

Highly oxidising fluids generated during serpentinite breakdown in subduction zones.

Project description:Subduction zones facilitate chemical exchanges between Earth's deep interior and volcanism that affects habitability of the surface environment. Lavas erupted at subduction zones are oxidized and release volatile species. These features may reflect a modification of the oxidation state of the sub-arc mantle by hydrous, oxidizing sulfate and/or carbonate-bearing fluids derived from subducting slabs. But the reason that the fluids are oxidizing has been unclear. Here we use theoretical chemical mass transfer calculations to predict the redox state of fluids generated during serpentinite dehydration. Specifically, the breakdown of antigorite to olivine, enstatite, and chlorite generates fluids with high oxygen fugacities, close to the hematite-magnetite buffer, that can contain significant amounts of sulfate. The migration of these fluids from the slab to the mantle wedge could therefore provide the oxidized source for the genesis of primary arc magmas that release gases to the atmosphere during volcanism. Our results also show that the evolution of oxygen fugacity in serpentinite during subduction is sensitive to the amount of sulfides and potentially metal alloys in bulk rock, possibly producing redox heterogeneities in subducting slabs.

| S-EPMC5583334 | biostudies-literature

Melting of subducted sediments reconciles geophysical images of subduction zones.

Project description:Sediments play a key role in subduction. They help control the chemistry of arc volcanoes and the location of seismic hazards. Here, we present a new model describing the fate of subducted sediments that explains magnetotelluric models of subduction zones, which commonly show an enigmatic conductive anomaly at the trenchward side of volcanic arcs. In many subduction zones, sediments will melt trenchward of the source region for arc melts. High-pressure experiments show that these sediment melts will react with the overlying mantle wedge to produce electrically conductive phlogopite pyroxenites. Modelling of the Cascadia and Kyushu subduction zones shows that the products of sediment melting closely reproduce the magnetotelluric observations. Melting of subducted sediments can also explain K-rich volcanic rocks that are produced when the phlogopite pyroxenites melt during slab roll-back events. This process may also help constrain models for subduction zone seismicity. Since melts and phlogopite both have low frictional strength, damaging thrust earthquakes are unlikely to occur in the vicinity of the melting sediments, while increased fluid pressures may promote the occurrence of small magnitude earthquakes and episodic tremor and slip.

| S-EPMC7910547 | biostudies-literature

Zinc isotope evidence for sulfate-rich fluid transfer across subduction zones.

Project description:Subduction zones modulate the chemical evolution of the Earth's mantle. Water and volatile elements in the slab are released as fluids into the mantle wedge and this process is widely considered to result in the oxidation of the sub-arc mantle. However, the chemical composition and speciation of these fluids, which is critical for the mobility of economically important elements, remain poorly constrained. Sulfur has the potential to act both as oxidizing agent and transport medium. Here we use zinc stable isotopes (?66Zn) in subducted Alpine serpentinites to decipher the chemical properties of slab-derived fluids. We show that the progressive decrease in ?66Zn with metamorphic grade is correlated with a decrease in sulfur content. As existing theoretical work predicts that Zn-SO42- complexes preferentially incorporate heavy ?66Zn, our results provide strong evidence for the release of oxidized, sulfate-rich, slab serpentinite-derived fluids to the mantle wedge.

| S-EPMC5171646 | biostudies-literature

Tsunamigenic potential of crustal faults and subduction zones in the Mediterranean.

Project description:We compiled a database and systematically evaluated tsunamigenic potential of all up-to-date known crustal fault systems and subduction zones in the entire Mediterranean region that has experienced several catastrophic tsunamis in historical times. The task is accomplished by means of numerical modeling of tsunami generation and propagation. We have systematically simulated all representative ruptures populating known crustal faults and subduction interfaces with magnitudes ranging from 6.1 up to expected Mwmax. Maximum tsunami heights calculated everywhere along the coasts allowed us to classify the sources in terms of their tsunamigenic potential and to estimate their minimum tsunamigenic magnitude. Almost every source in the Mediterranean, starting from Mw = 6.5, is capable to produce local tsunami at the advisory level (wave height >20 cm and ≤50 cm). In respect to the watch level (wave height >50 cm) larger magnitudes are needed (Mw ≥ 6.9). Faults behave more heterogeneously in the context of far field early warning. De-aggregation of the database at any selected coastal location can reveal relevant sources of tsunami hazard for this location. Our compilation blueprints methodology that, if completed with source recurrence rates and site-specific amplification factors, can be considered as a backbone for development of optimal early warning strategies by Mediterranean tsunami warning providers.

| S-EPMC6416261 | biostudies-literature