Dataset Information
Crystal structures of 4-{(E)-3-[(imino-?5-aza-nyl-idene)amino]-prop-1-en-yl}-N,N-di-methyl-imidazole-1-sulfonamide and 2-[(imino-?5-aza-nyl-idene)amino]-4-{(E)-3-[(imino-?5-aza-nyl-idene)amino]-prop-1-en-yl}-N,N-di-methyl-imidazole-1-sulfonamide.
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ABSTRACT:
SUBMITTER: Cruz LM
PROVIDER: S-EPMC6505610 | biostudies-literature | 2019 May
REPOSITORIES: biostudies-literature
Publications
Crystal structures of 4-{(<i>E</i>)-3-[(imino-λ<sup>5</sup>-aza-nyl-idene)amino]-prop-1-en-yl}-<i>N</i>,<i>N</i>-di-methyl-imidazole-1-sulfonamide and 2-[(imino-λ<sup>5</sup>-aza-nyl-idene)amino]-4-{(<i>E</i>)-3-[(imino-λ<sup>5</sup>-aza-nyl-idene)amino]-prop-1-en-yl}-<i>N</i>,<i>N</i>-di-methyl-imidazole-1-sulfonamide.
Acta crystallographica. Section E, Crystallographic communications 20190425 Pt 5
The structures of two azide containing imidazole derivatives are reported. Allylic azides are fairly reactive making them attractive starting compounds to convert into amides. The first, C<sub>8</sub>H<sub>12</sub>N<sub>6</sub>O<sub>2</sub>S, contains one azide group with an N<sub>α</sub>-N<sub>β</sub> distance of 1.229 (2) Å and an N<sub>β</sub>-N<sub>γ</sub> distance of 1.128 (2) Å. The second, C<sub>8</sub>H<sub>11</sub>N<sub>9</sub>O<sub>2</sub>S, contains two azide groups with an average N< ...[more]