Unknown

Dataset Information

0

Chlorido-(2,2'-{[2-(1-methyl-1H-imidazol-2-yl-?N 3)imidazolidine-1,3-diyl-?N]bis-(methyl-ene)}bis-(1-methyl-1H-imidazole-?N 3))copper(II) perchlorate.

ABSTRACT: In the crystal structure of the title complex, [CuCl(C17H24N8)]ClO4, the copper(II) metal exhibits an N4Cl penta-coordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methyl-imidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Inter-molecular inter-actions take place at two of the 1-methyl--imidazole rings in the form of parallel-displaced ?-? stacking inter-actions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5.

SUBMITTER: Padilha DDS 

PROVIDER: S-EPMC6505613 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Chlorido-(2,2'-{[2-(1-methyl-1<i>H</i>-imidazol-2-yl-κ<i>N</i> <sup>3</sup>)imidazolidine-1,3-diyl-κ<i>N</i>]bis-(methyl-ene)}bis-(1-methyl-1<i>H</i>-imidazole-κ<i>N</i> <sup>3</sup>))copper(II) perchlorate.

Padilha Diego da Silva DDS   Padilha Diego da Silva DDS   Scarpellini Marciela M  

Acta crystallographica. Section E, Crystallographic communications 20190402 Pt 5

In the crystal structure of the title complex, [CuCl(C<sub>17</sub>H<sub>24</sub>N<sub>8</sub>)]ClO<sub>4</sub>, the copper(II) metal exhibits an N<sub>4</sub>Cl penta-coordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methyl-imidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Inter-molecular inter-actions take place at two of the 1-methyl--imidazole rings in th  ...[more]

Similar Datasets

Unknown Di-chlorido-bis-[1-(2,4,6-tri-methyl-phen-yl)-1H-imidazole-κN (3)]copper(II).
| S-EPMC3884270 | biostudies-literature
Unknown Bis[μ-1,1'-methyl-enebis(1H-imidazole)-κN:N]bis-[dichloridocobalt(II)].
| S-EPMC3099993 | biostudies-literature
Unknown Aqua-bis(1H-imidazole-κN)bis-(4-methyl-benzoato-κO,O')cadmium(II).
| S-EPMC2961263 | biostudies-literature
Unknown Bis[2-(3,4-disulfanylphen-yl)acetato]bis-(2-methyl-1H-imidazole-κN)zinc(II).
| S-EPMC2970003 | biostudies-literature
Unknown Aqua-bis(1H-imidazole-κN)bis-(4-methyl-benzoato)-κO;κO,O'-nickel(II).
| S-EPMC2961080 | biostudies-literature
Unknown catena-Poly[[bis-(1-ethyl-1H-imidazole-?N)cadmium]-di-?-chlorido-[(1-ethyl-1H-imidazole-?N)cadmium]-di-?-chlorido-[(1-ethyl-1H-imidazole-?N)cadmium]-di-?-chlorido-[bis-(1-ethyl-1H-imidazole-?N)cadmium]].
| S-EPMC3238745 | biostudies-literature
Unknown 6,6'-Dimethyl-2,2'-[imidazolidine-1,3-diyl-bis(methyl-ene)]diphenol.
| S-EPMC3998388 | biostudies-literature
Unknown Crystal structure of bis-(2-methyl-1H-imidazol-3-ium) tetra-chlorido-cobaltate(II).
| S-EPMC4555386 | biostudies-literature
Unknown Bis(N,N-dimethyl-formamide-κO)bis-(1-methyl-imidazole-2-carbaldehyde oximato-κN,O)manganese(III) perchlorate.
| S-EPMC2959584 | biostudies-literature
Unknown Diaqua-bis(2,2'-bi-1H-imidazole-κN,N)nickel(II) bis-(3-methyl-benzoate) 3-methyl-benzoic acid disolvate.
| S-EPMC2971984 | biostudies-literature