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Comparing the Self-Assembly of Sexiphenyl-Dicarbonitrile on Graphite and Graphene on Cu(111).


ABSTRACT: A comparative study on the self-assembly of sexiphenyl-dicarbonitrile on highly oriented pyrolytic graphite and single-layer graphene on Cu(111) is presented. Despite an overall low molecule-substrate interaction, the close-packed structures exhibit a peculiar shift repeating every four to five molecules. This shift has hitherto not been reported for similar systems and is hence a unique feature induced by the graphitic substrates.

SUBMITTER: Schmidt N 

PROVIDER: S-EPMC6519158 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Comparing the Self-Assembly of Sexiphenyl-Dicarbonitrile on Graphite and Graphene on Cu(111).

Schmidt Nico N   Li Jun J   Gottardi Stefano S   Moreno-Lopez Juan Carlos JC   Enache Mihaela M   Monjas Leticia L   van der Vlag Ramon R   Havenith Remco W A RWA   Hirsch Anna K H AKH   Stöhr Meike M  

Chemistry (Weinheim an der Bergstrasse, Germany) 20190312 19


A comparative study on the self-assembly of sexiphenyl-dicarbonitrile on highly oriented pyrolytic graphite and single-layer graphene on Cu(111) is presented. Despite an overall low molecule-substrate interaction, the close-packed structures exhibit a peculiar shift repeating every four to five molecules. This shift has hitherto not been reported for similar systems and is hence a unique feature induced by the graphitic substrates. ...[more]

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