Browse
Submit Data
Databases
API
Help

Dataset Information

12 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Phase-Transited Lysozyme-Driven Formation of Self-Supported Co₃O₄@C Nanomeshes for Overall Water Splitting.

ABSTRACT: The development of highly efficient catalysts for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is of paramount importance in water splitting. Herein, a phase-transited lysozyme (PTL) is employed as the platform to synthesize nitrogen-doped Co₃O₄@C nanomesh with rich oxygen vacancies supported on the nickel foam (N-Co₃O₄@C@NF). This PTL-driven N-Co₃O₄@C@NF integrates the advantages of porous structure, high exposure of surface atoms, strong synergetic effect between the components and unique 3D electrode configuration, imparting exceptional activity in catalyzing both HER and OER. Remarkably, an alkaline electrolyzer assembled by N-Co₃O₄@C@NF as both cathode and anode delivers a current density of 10 mA cm^-2 at an ultralow cell voltage of 1.40 V, which is not only much lower than that of the commercially noble Pt/C and IrO₂/C catalyst couple (≈1.61 V) but also a new record for the overall water splitting. The finding may open new possibilities for the design of bifunctional electrocatalysts for application in practical water electrolysis.

SUBMITTER: Ha Y

PROVIDER: S-EPMC6548951 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Ultrafine Co3O4 nanolayer-shelled CoWP nanowire array: a bifunctional electrocatalyst for overall water splitting.

Project description:The development of bifunctional electrocatalysts based on highly efficient non-noble metals is pivotal for overall water splitting. Here, a composite electrode of Co3O4@CoWP is synthesized, where an ultrathin layer composed of Co3O4 nanoparticles is grown on CoWP nanowires supported on a carbon cloth (CC). The Co3O4@CoWP/CC electrode exhibits excellent electrocatalytic activity and improved kinetics towards both the oxygen and hydrogen evolution reactions (OER and HER). The Co3O4@CoWP/CC electrode achieves a current density of 10 mA cm-2 at a low overpotential of 269 mV for the OER and -10 mA cm-2 at 118 mV for the HER in 1.0 M KOH solution. The voltage applied to a two-electrode water electrolyzer for overall water splitting, while employing the Co3O4@CoWP/CC electrode as both an anode and a cathode, in order to reach a current density of 10 mA cm-2, is 1.61 V, which is better than that for the majority of reported non-noble electrocatalysts. Moreover, the Co3O4@CoWP/CC electrode exhibits good stability over 24 h with slight attenuation. The electrode benefits from the enhanced adsorption of oxygen intermediates on Co3O4 during the OER, the increased ability for water dissociation and the optimized H adsorption/desorption ability of CoWP nanowires during the HER. This study provides a feasible approach for cost-effective and high-performance non-noble metal bifunctional catalysts for overall water electrolysis.

| S-EPMC9055948 | biostudies-literature

Hollow Nanocages of NixCo1-xSe for Efficient Zinc-Air Batteries and Overall Water Splitting.

Project description:Developing Earth-abundant, highly efficient, and anti-corrosion electrocatalysts to boost the oxygen evolution reaction (OER), oxygen reduction reaction (ORR), and hydrogen evolution reaction (HER) for the Zn-air battery (ZAB) and for overall water splitting is imperative. In this study, a novel process starting with Cu2O cubes was developed to fabricate hollow NixCo1-xSe nanocages as trifunctional electrocatalysts for the OER, ORR, and HER and a reasonable formation mechanism was proposed. The Ni0.2Co0.8Se nanocages exhibited higher OER activity than its counterparts with the low overpotential of 280 mV at 10 mA cm-2. It also outperformed the other samples in the HER test with a low overpotential of 73 mV at 10 mA cm-2. As an air-cathode of a self-assembled rechargeable ZAB, it exhibited good performance, such as an ultralong cycling lifetime of > 50 h, a high round-trip efficiency of 60.86%, and a high power density of 223.5 mW cm-2. For the application in self-made all-solid-state ZAB, it also demonstrated excellent performance with a power density of 41.03 mW cm-2 and an open-circuit voltage of 1.428 V. In addition, Ni0.2Co0.8Se nanocages had superior performance in a practical overall water splitting, in which only 1.592 V was needed to achieve a current density of 10 mA cm-2. These results show that hollow NixCo1-xSe nanocages with an optimized Ni-to-Co ratio are a promising cost-effective and high-efficiency electrocatalyst for ZABs and overall water splitting in alkaline solutions.

| S-EPMC7770759 | biostudies-literature

(Fe0.2Ni0.8)0.96S tubular spheres supported on Ni foam as an efficient bifunctional electrocatalyst for overall water splitting.

Project description:Earth-abundant and efficient bifunctional electrocatalysts for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) are highly significant for renewable energy systems. However, the performance of existing electrocatalysts is usually restricted by the low electroic conductivity and the limited amount of exposed active sites. In this work, (Fe0.2Ni0.8)0.96S tubular spheres supported on Ni foam have been prepared by a sulfuration of FeNi layered double hydroxide spheres grown on Ni foam. Benefiting from the unique tubular sphere architecture, the rich inner defects and the enhanced electron interactions between Fe, Ni and S, this electrocatalyst shows low overpotential of 48 mV for HER at 10 mA cm-2 in 1.0 mol L-1 KOH solution, which is one of the lowest value of non-previous electrocatalyts for HER in alkaline electrolyte. Furthermore, assembled this versatile electrode as an alkaline electrolyzer for overall water splitting, a current density of 10 mA cm-2 is achieved at a low cell voltage of 1.56 V, and reach up to 30 mA cm-2 only at an operating cell voltage of 1.65 V.

| S-EPMC6013453 | biostudies-literature

Microflower-like Co9S8@MoS2 heterostructure as an efficient bifunctional catalyst for overall water splitting.

Project description:The development of a distinguished and high-performance catalyst for H2 and O2 generation is a rational strategy for producing hydrogen fuel via electrochemical water splitting. Herein, a flower-like Co9S8@MoS2 heterostructure with effective bifunctional activity was achieved using a one-pot approach via the hydrothermal treatment of metal-coordinated species followed by pyrolysis under an N2 atmosphere. The heterostructures exhibited a 3D interconnected network with a large electrochemical active surface area and a junctional complex with hydrogen evolution reaction (HER) catalytic activity of MoS2 and oxygen evolution reaction (OER) catalytic activity of Co9S8, exhibiting low overpotentials of 295 and 103 mV for OER and HER at 10 mA cm-2 current density, respectively. Additionally, the catalyst-assembled electrolyser provided favourable catalytic activity and strong durability for overall water splitting in 1 M KOH electrolyte. The results of the study highlight the importance of structural engineering for the design and preparation of cost-effective and efficient bifunctional electrocatalysts.

| S-EPMC9377311 | biostudies-literature

One-Step Synthesis of a Self-Supported Copper Phosphide Nanobush for Overall Water Splitting.

Project description:Developing cheap, stable, and efficient electrocatalysts is of extreme importance in the effort to replace noble metal electrocatalysts for use in the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). We report a three-dimensional self-supported Cu3P nanobush (NB) catalyst directly grown on a copper mesh via a one-step method. This nanostructure exhibits a superior catalytic activity of achieving a current density of 10 mA cm-2 at 120 mV and exhibits a long-term stability in acid solutions. It shows a Tafel slope of 72 mV dec-1 and an onset potential of -44 mV. This catalyst displays a good catalytic activity in basic electrolytes, reaching a current density of 10 mA cm-2 at the overpotential values of 252 and 380 mV for HER and OER, respectively. The bifunctional Cu3P NB/Cu catalyst exhibits better catalytic performances than the Pt/C and IrO2 catalysts in a two-electrode electrolyzer for overall water splitting.

| S-EPMC6640776 | biostudies-literature

Electric-Field-Treated Ni/Co3O4 Film as High-Performance Bifunctional Electrocatalysts for Efficient Overall Water Splitting.

Project description: Not available

| S-EPMC9307702 | biostudies-literature

Construction of Hierarchical Co-Fe Oxyphosphide Microtubes for Electrocatalytic Overall Water Splitting.

Project description:Development of efficient electrocatalysts is a crucial requirement to build water splitting systems for the production of clean and sustainable fuels. This goal could be achieved by fine-tuning the composition and structure of the electrocatalytic materials. Here, a facile self-templated synthetic strategy is developed for the fabrication of hierarchical Co-Fe oxyphosphide microtubes (MTs). Fe-based metal-organic compound microrods are first synthesized as the self-sacrificing template. Afterward, the Fe-based precursors are converted into hierarchical Co-Fe layered double hydroxide MTs through a hydrothermal approach, which are then transformed into the hierarchical Co-Fe oxyphosphide MTs by a phosphidation treatment. Benefiting from the synergistic effect of the compositions and the advantages of the hierarchical hollow structure, the obtained electrocatalyst exhibits enhanced performance for overall water splitting.

| S-EPMC6724352 | biostudies-literature

An Al-doped SrTiO3 photocatalyst maintaining sunlight-driven overall water splitting activity for over 1000 h of constant illumination.

Project description:Photocatalytic water splitting is a viable approach to the large-scale production of renewable solar hydrogen. The apparent quantum yield for this reaction has been improved, but the lifespan of photocatalysts functioning under sunlight at ambient pressure have rarely been examined, despite the critical importance of this factor in practical applications. Herein, we show that Al-doped SrTiO3 (SrTiO3:Al) loaded with a RhCrO x (rhodium chromium oxide) cocatalyst splits water with an apparent quantum yield greater than 50% at 365 nm. Moreover, following the photodeposition of CoOOH and TiO2, this material maintains 80% of its initial activity and a solar-to-hydrogen energy conversion efficiency greater than or equal to 0.3% over a span of 1300 h under constant illumination by simulated sunlight at ambient pressure. This result is attributed to reduced dissolution of Cr in the cocatalyst following the oxidative photodeposition of CoOOH. The photodeposition of TiO2 further improves the durability of this photocatalyst. This work demonstrates a concept that could allow the design of long-term, large-scale photocatalyst systems for practical sunlight-driven water splitting.

| S-EPMC6430014 | biostudies-literature

Perovskite Oxynitride Solid Solutions of LaTaON2-CaTaO2N with Greatly Enhanced Photogenerated Charge Separation for Solar-Driven Overall Water Splitting.

Project description:The search for solar-driven photocatalysts for overall water splitting has been actively pursued. Although metal oxynitrides with metal d0/d10-closed shell configuration are very promising candidates in terms of their visible light absorption, they usually suffer from serious photo-generated charge recombination and thus, little photoactivity. Here, by forming their solid solutions of LaTaON2 and CaTaO2N, which are traditionally considered to be inorganic yellow-red pigments but have poor photocatalytic activity, a class of promising solar-driven photocatalysts La1- x Ca x TaO1+yN2- y (0 ≤ x, y ≤ 1) are explored. In particular, the optimal photocatalyst with x = 0.9 has the ability of realizing overall water splitting with stoichiometric H2/O2 ratio under the illumination of both AM1.5 simulated solar light and visible light. The modulated key parameters including band structure, Ta bonding environment, defects concentration, and band edge alignments revealed in La0.1Ca0.9TaO1+ y N2- y have substantially promoted the separation of photogenerated charge carriers with sufficient energetics for water oxidation and reduction reactions. The results obtained in this study provide an important candidate for designing efficient solar-driven photocatalysts for overall water splitting.

| S-EPMC7816695 | biostudies-literature

Self-activated superhydrophilic green ZnIn2S4 realizing solar-driven overall water splitting: close-to-unity stability for a full daytime.

Project description:Engineering an efficient semiconductor to sustainably produce green hydrogen via solar-driven water splitting is one of the cutting-edge strategies for carbon-neutral energy ecosystem. Herein, a superhydrophilic green hollow ZnIn2S4 (gZIS) was fabricated to realize unassisted photocatalytic overall water splitting. The hollow hierarchical framework benefits exposure of intrinsically active facets and activates inert basal planes. The superhydrophilic nature of gZIS promotes intense surface water molecule interactions. The presence of vacancies within gZIS facilitates photon energy utilization and charge transfer. Systematic theoretical computations signify the defect-induced charge redistribution of gZIS enhancing water activation and reducing surface kinetic barriers. Ultimately, the gZIS could drive photocatalytic pure water splitting by retaining close-to-unity stability for a full daytime reaction with performance comparable to other complex sulfide-based materials. This work reports a self-activated, single-component cocatalyst-free gZIS with great exploration value, potentially providing a state-of-the-art design and innovative aperture for efficient solar-driven hydrogen production to achieve carbon-neutrality.

| S-EPMC10667227 | biostudies-literature