Ontology highlight
ABSTRACT:
SUBMITTER: Hood TM
PROVIDER: S-EPMC6549213 | biostudies-literature | 2019 Jun
REPOSITORIES: biostudies-literature
Hood Thomas M TM Leforestier Baptiste B Gyton Matthew R MR Chaplin Adrian B AB
Inorganic chemistry 20190522 11
The synthesis and characterization of a homologous series of five-coordinate rhodium(III) and iridium(III) complexes of PNP (2,6-( tBu<sub>2</sub>PCH<sub>2</sub>)<sub>2</sub>C<sub>5</sub>H<sub>3</sub>N) and PONOP (2,6-( tBu<sub>2</sub>PO)<sub>2</sub>C<sub>5</sub>H<sub>3</sub>N) pincer ligands are described: [M(PNP)(biph)][BAr<sup>F</sup><sub>4</sub>] (M = Rh, 1a; Ir, 1b; biph = 2,2'-biphenyl; Ar<sup>F</sup> = 3,5-(CF<sub>3</sub>)<sub>2</sub>C<sub>6</sub>H<sub>3</sub>) and [M(PONOP)(biph)][BAr<su ...[more]