Ontology highlight
ABSTRACT:
SUBMITTER: Gordon JB
PROVIDER: S-EPMC6556537 | biostudies-literature | 2019 Feb
REPOSITORIES: biostudies-literature
Gordon Jesse B JB Vilbert Avery C AC Siegler Maxime A MA Lancaster Kyle M KM Moënne-Loccoz Pierre P Goldberg David P DP
Journal of the American Chemical Society 20190218 8
The synthesis and characterization of a Co(II) dithiolato complex Co(Me<sub>3</sub>TACN)(S<sub>2</sub>SiMe<sub>2</sub>) (1) are reported. Reaction of 1 with O<sub>2</sub> generates a rare thiolate-ligated cobalt-superoxo species Co(O<sub>2</sub>)(Me<sub>3</sub>TACN)(S<sub>2</sub>SiMe<sub>2</sub>) (2) that was characterized spectroscopically and structurally by resonance Raman, EPR, and X-ray absorption spectroscopies as well as density functional theory. Metal-superoxo species are proposed to S- ...[more]