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Electron spin density matching for cross-effect dynamic nuclear polarization.


ABSTRACT: A new design principle for a mixed broad (TEMPO) and narrow (Trityl) line radical to boost the dynamic nuclear polarization efficiency is electron spin density matching, suggesting a polarizing agent of one Trityl tethered to at least two TEMPO moieties.

SUBMITTER: Li Y 

PROVIDER: S-EPMC6597276 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Electron spin density matching for cross-effect dynamic nuclear polarization.

Li Yuanxin Y   Equbal Asif A   Tagami Kan K   Han Songi S  

Chemical communications (Cambridge, England) 20190601 53


A new design principle for a mixed broad (TEMPO) and narrow (Trityl) line radical to boost the dynamic nuclear polarization efficiency is electron spin density matching, suggesting a polarizing agent of one Trityl tethered to at least two TEMPO moieties. ...[more]

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